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Cl

Chlorine

Chlorine (Cl) is a reactive nonmetal with atomic number 17 and an atomic mass of 35.45. Its electron configuration is [Ne] 3s2 3p5, which gives it 7 valence electrons.

Chlorine key data

Symbol Cl
Atomic number 17
Atomic mass (standard atomic weight) 35.45
Molar mass 35.45 g/mol
Protons 17
Neutrons (most abundant isotope, chlorine-35) 18
Electrons (neutral atom) 17
Valence electrons 7
Category Reactive nonmetal
Period 3
Group 17
Block p-block
Noble gas notation [Ne] 3s2 3p5
Full electron configuration 1s2 2s2 2p6 3s2 3p5
Electrons per shell 2, 8, 7

Atomic mass: IUPAC CIAAW abridged standard atomic weights, 2024. Most abundant isotope: NIST Atomic Weights and Isotopic Compositions.

The values are facts and free to use; this page’s selection and presentation are © 2026 ScienceQuest.

Measured properties of chlorine

From PubChem, the US National Institutes of Health. Public domain.

Melting point 171.65 K (−101.5 °C), 94th of 103 by melting point
Boiling point 239.11 K (−34.04 °C), 83rd of 93 by boiling point
Density 0.003214 g/cm³, 89th of 96 by density
State at room temperature Gas
Electronegativity 3.16 (Pauling), 3rd of 95 by electronegativity
Van der Waals radius 175 pm, 84th of 99 by atomic radius
First ionisation energy 12.968 eV (1251.2 kJ/mol), 9th of 102 by first ionisation energy
Electron affinity 3.617 eV (349 kJ/mol), 1st of 57 by electron affinity
Common oxidation states +7, +5, +1, −1
Discovered 1774

Each rank counts down from the highest value, among the elements PubChem’s table gives one for, and links to that property ranked across the whole table. All of them are collected under periodic trends.

Chlorine electron configuration

The full electron configuration of chlorine is 1s2 2s2 2p6 3s2 3p5. With the noble-gas core collapsed it is [Ne] 3s2 3p5, and the outermost subshell is 3p5.

Bohr model of chlorine (Cl): a nucleus and three shells holding 2, 8 and 7 electrons from the inside out.
Bohr model of chlorine (Cl). Image © ScienceQuest, CC BY 4.0: free to reuse with credit to ScienceQuest and a link to this page, as the image licence explains.
Orbital box diagram of chlorine (Cl), 1s2 2s2 2p6 3s2 3p5: one box per orbital, filled by Hund’s rule, showing one unpaired electron, in 3p.
Orbital diagram of chlorine (Cl). Image © ScienceQuest, CC BY 4.0: free to reuse with credit to ScienceQuest and a link to this page, as the image licence explains.

Why group and block follow from this is set out in how the periodic table maps electron configuration, and the electron configuration of every element is listed on one page.

Mass of one chlorine atom

A molar mass is grams per mole, so dividing by the Avogadro constant gives the mass of a single atom, or for an element with more than one natural isotope the average mass of its atoms, and the reciprocal gives how many atoms sit in a gram.

Mass of one atom

  1. one atom = 35.45 / (6.02214076 × 10²³)
  2. = 5.8866 × 10⁻²³ g

Atoms in one gram

  1. atoms per gram = 6.02214076 × 10²³ / 35.45
  2. = 1.6988 × 10²² atoms

Chlorine on the periodic table

Chlorine is in period 3, group 17, in the p-block.

The other elements of group 17 are fluorine, bromine, iodine, astatine and tennessine.

The rest of period 3

Work with chlorine