Skip to content
ScienceQuest
F

Fluorine

Fluorine (F) is a reactive nonmetal with atomic number 9 and an atomic mass of 18.998. Its electron configuration is [He] 2s2 2p5, which gives it 7 valence electrons.

Fluorine key data

Symbol F
Atomic number 9
Atomic mass (standard atomic weight) 18.998
Molar mass 18.998 g/mol
Protons 9
Neutrons (most abundant isotope, fluorine-19) 10
Electrons (neutral atom) 9
Valence electrons 7
Category Reactive nonmetal
Period 2
Group 17
Block p-block
Noble gas notation [He] 2s2 2p5
Full electron configuration 1s2 2s2 2p5
Electrons per shell 2, 7

Atomic mass: IUPAC CIAAW abridged standard atomic weights, 2024. Most abundant isotope: NIST Atomic Weights and Isotopic Compositions.

The values are facts and free to use; this page’s selection and presentation are © 2026 ScienceQuest.

Measured properties of fluorine

From PubChem, the US National Institutes of Health. Public domain. The discovery year is the year fluorine was first isolated, from Wikipedia’s timeline of chemical element discoveries, in place of PubChem’s 1670. The electron affinity is the measured value for fluorine, from Wikipedia’s electron affinity data page, in place of PubChem’s 3.339 eV.

Melting point 53.53 K (−219.62 °C), 100th of 103 by melting point
Boiling point 85.03 K (−188.12 °C), 89th of 93 by boiling point
Density 0.001696 g/cm³, 91st of 96 by density
State at room temperature Gas
Electronegativity 3.98 (Pauling), 1st of 95 by electronegativity
Van der Waals radius 135 pm, 98th of 99 by atomic radius
First ionisation energy 17.423 eV (1681.1 kJ/mol), 3rd of 102 by first ionisation energy
Electron affinity 3.40119 eV (328.165 kJ/mol), 2nd of 57 by electron affinity
Common oxidation states −1
Discovered 1886

Each rank counts down from the highest value, among the elements PubChem’s table gives one for, and links to that property ranked across the whole table. All of them are collected under periodic trends.

Fluorine electron configuration

The full electron configuration of fluorine is 1s2 2s2 2p5. With the noble-gas core collapsed it is [He] 2s2 2p5, and the outermost subshell is 2p5.

Bohr model of fluorine (F): a nucleus and two shells holding 2 and 7 electrons from the inside out.
Bohr model of fluorine (F). Image © ScienceQuest, CC BY 4.0: free to reuse with credit to ScienceQuest and a link to this page, as the image licence explains.
Orbital box diagram of fluorine (F), 1s2 2s2 2p5: one box per orbital, filled by Hund’s rule, showing one unpaired electron, in 2p.
Orbital diagram of fluorine (F). Image © ScienceQuest, CC BY 4.0: free to reuse with credit to ScienceQuest and a link to this page, as the image licence explains.

Why group and block follow from this is set out in how the periodic table maps electron configuration, and the electron configuration of every element is listed on one page.

Mass of one fluorine atom

A molar mass is grams per mole, so dividing by the Avogadro constant gives the mass of a single atom, or for an element with more than one natural isotope the average mass of its atoms, and the reciprocal gives how many atoms sit in a gram.

Mass of one atom

  1. one atom = 18.998 / (6.02214076 × 10²³)
  2. = 3.1547 × 10⁻²³ g

Atoms in one gram

  1. atoms per gram = 6.02214076 × 10²³ / 18.998
  2. = 3.1699 × 10²² atoms

Fluorine on the periodic table

Fluorine is in period 2, group 17, in the p-block.

The other elements of group 17 are chlorine, bromine, iodine, astatine and tennessine.

The rest of period 2

Work with fluorine